期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 44, 页码 5622-5625出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03204a
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资金
- University of Nottingham
- GlaxoSmithKline
The enantioselective nickel-catalyzed desymmetrization of allenyl cyclohexa-2,5-dienones by reaction with arylboronic acids is described. Nickel-catalyzed arylation of the allene gives allylnickel species, which undergo cyclization by 1,4-allylation to produce hexahydroindol-5-ones and hexahydrobenzofuran-5-ones with three contiguous stereocenters in high diastereo- and enantioselectivities.
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