期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 49, 页码 6360-6363出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03191f
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-
资金
- JSPS KAKENHI Grant [JP 16K13942]
Studies to convert nitroalkanes into amides and esters using I-2 and O-2 revealed in situ-generated iodine species facilitate the homolytic C-I bond cleavage of ,-diiodonitroalkanes, arguably in an autoinductive or autocatalytic manner. Consequently, we devised a rapid and economical I-2/O-2-based method to synthesise sterically hindered esters directly from primary nitroalkanes.
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