期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 24, 页码 3061-3064出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00763b
关键词
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资金
- Spanish Ministerio de Economia y Competitividad (MINECO) [IJC-2014-20097, CTQ2015-64579-C3-1-P]
We report here, for the first time, the existence of n * interactions in transition metal complexes containing carbonyl ligands. This interaction has been observed to be surprisingly abundant and to stabilize precise molecular conformations that maximize the overlap between the donor and acceptor orbitals.
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