期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 61, 页码 8446-8449出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03109f
关键词
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资金
- National Natural Science Foundation of China [21362002]
- Guangxi Natural Science Foundation of China [2016GXNSFEA380001, 2016GXNSFGA380005]
- State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources [CMEMR2017-A02, CMEMR2017-A07]
A novel palladium nanoparticle (NP)-metalated porous organic ligand (Pd NPs/POL-xantphos) has been prepared for the chemoselective decarbonylation of aldehydes. This heterogenous catalyst not only has excellent catalytic activity and chemoselectivity, but also holds high activity after 10 runs of reuse. The effective usage of this method is demonstrated through the synthesis of biofuels such as furfuryl alcohol (FFA) via the highly chemoselective decarbonylation of biomass-derived 5-hydroxy-methylfurfural (HMF) with a TON up to 1540. More importantly, 9-fluorenone could be obtained in one step through the decarbonylation of 2-bromobenzaldehyde by using this heterogeneous catalyst.
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