期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 31, 页码 3839-3842出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00341f
关键词
-
资金
- EPSRC-UK [EP/N022122/1, EP/M010554/1]
- European Commission Directorate General and Actinet JRC Userlab [ACTINET-I3-CP-CSA-JRP-232631]
- Natural Sciences and Engineering Research Council of Canada
- European Research Council (ERC) under the European Union's Horizon research and innovation programme [740311]
- EPSRC [EP/M010554/1, EP/N022122/1] Funding Source: UKRI
- European Research Council (ERC) [740311] Funding Source: European Research Council (ERC)
A new type of double uranium oxo cation [O-U-O-U-O](4+) is prepared by selective oxygen-atom abstraction from macrocyclic uranyl complexes using either boranes or silanes. A significant degree of multiple U?O bonding is evident throughout the U2O3 core, but either trans-,cis- or trans-,trans-OUOUO motifs can be isolated as boron- or silicon-capped oxo complexes. Further controlled deoxygenation of the borylated system is also possible.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据