期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 26, 页码 3219-3222出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00238j
关键词
-
资金
- National NSF of China [21772133, 21672154, 21432005]
A highly efficient direct C-H amination of BODIPYs has been accomplished through the Ag(I)-mediated nucleophilic addition of an amino radical to BODIPY at the C3-and/or C5-position and deprotonation processes under mild conditions. This protocol greatly streamlines the access to a variety of 3-aminated and 3,5-diaminated BODIPYs. The resulting BODIPYs with morpholine groups (3q and 4b) exhibit specific endoplasmic reticulum (ER)-localization capacities and negligible cytotoxicities, which would be potential ER-targeting reagents.
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