期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 46, 页码 5915-5918出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03123a
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资金
- Elements Strategy Initiative for Catalysts & Batteries (ESICB)
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) of Japan [12024046]
- Japan Society for the Promotion of Science (JSPS) [17H01182]
A single rhodium atom was precisely doped into a gold cluster Au-34 stabilized by poly(N-vinyl-2-pyrrolidone) (Au:PVP) as revealed by mass spectrometry. The Rh-atom-doped Au:PVP exhibited remarkable catalytic activity for hydrogenation reactions of olefins, which was much higher than that of recently reported Pd-atom-doped Au:PVP.
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