期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 34, 页码 4314-4316出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/C8CC00985F
关键词
-
资金
- National Natural Science Foundation of China [21631001, 21372006, U1532141]
- Ministry of Education, the Education Department of Anhui Province
- 211 Project of the Anhui University
A novel Ag-Cu bimetallic nanocluster, Ag40.13Cu13.87S19(tBuS)(20)(tBuSO(3))(12), has been synthesized by precise control. The crystal structure reveals that the alloy cluster consists of a Cu10Ag2S7 core, a M-42(tBuS)(20)(tBuSO(3))(12) shell and another 12 bare S atoms. The sulfonate ligand is observed in NCs for the first time via in situ oxidation of thiolate.
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