期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 32, 页码 3989-3992出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01876f
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资金
- Canon Foundation
- Murata Overseas Scholarship for Overseas Research Activities
- SNF [200021L_157146]
- JSPS KAKENHI [15KK0186, 15H05808, 15K21707, 2702]
- Fund for the Promotion of Joint International Research (Fostering Joint International Research)
- International Joint Research Promotion Program of Osaka University
- Swiss National Science Foundation (SNF) [200021L_157146] Funding Source: Swiss National Science Foundation (SNF)
- Grants-in-Aid for Scientific Research [15H05808, 15K21707, 15KK0186] Funding Source: KAKEN
A well-defined silica-supported molybdenum dioxo species, ( SiO)(2)Mo(O)(2), is prepared by grafting Mo(O)(2)[OSi(OtBu)(3)](2) on partially dehydroxylated silica SiO2-700, followed by thermal treatment under high-vaccum and calcination. Activated by an organo-silicon agent the resulting material is active for olefin metathesis at 30 degrees C.
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