期刊
CHEMCATCHEM
卷 10, 期 14, 页码 3049-3056出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201800360
关键词
electrochemistry; fuel cells; gold; oxygen; reduction
资金
- National Key RD Plan of China [2016YFB0101308]
- National Natural Science Foundation of China [21476104, 21676135]
- National Scientific Instrument Develop Major Project of National Natural Science Foundation of China [51627810]
- Joint Funds of the National Natural Science Foundation and Liaoning of China [U1508202]
- Natural Science Foundation for Distinguished Young Scholars of Jiangsu Province [BK20150009]
- PAPD of Jiangsu Higher Education Institutions
- Six Talent Peaks Program of Jiangsu Province
- Fundamental Research Funds for the Central Universities, China
Long-term stable and high active catalysts for oxygen reduction reaction (ORR) are required for the commercialization of proton exchange membrane fuel cells (PEMFCs). Platinum (Pt) catalyst is the preferred choose for ORR, but the stability and activity of existing Pt catalyst are unsatisfactory for the commercialization of PEMFCs. Here the ternary Pt-Au-Ni/C and binary Pt-Ni/C are synthesized by a rapid microwave-assisted polyol reduction. The Pt-Au-Ni/C exhibits superior ORR activity to both of Pt-Ni/C and commercial Pt/C. Moreover, the Pt-Au-Ni/C exhibited the long-term stability in both of half-cell and single-cell accelerated degradation tests. The above results indicate that the addition of Au into binary Pt-Ni catalyst can not only enhance the stability but also improve the electrocatalytic activity.
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