期刊
CELLULOSE
卷 25, 期 8, 页码 4513-4523出版社
SPRINGER
DOI: 10.1007/s10570-018-1897-x
关键词
Cellulose nanoparticles; Ionic liquid; Anti-solvent; Kamlet-Taft parameters; Hydrogen bond
资金
- National Natural Science Foundation of China [31370556]
- Beijing Municipality Science and Technology Planning Project [D161100002116001]
In this work, cellulose nanoparticles regenerated by water, methanol, ethanol and n-propanol as the anti-solvents from ionic liquid solution were studied systematically. Crystallinity and enthalpy in cellulose degradation of the regenerated cellulose decreased in the order water > methanol > ethanol > n-propanol. Nevertheless, the thermal stability of the regenerated cellulose showed an opposite trend. In addition, morphology of regenerated cellulose changed sharply with the variation of anti-solvents. Moreover, we introduced Kamlet-Taft parameters of anti-solvents to analyze the crystallinity, enthalpy in cellulose degradation and thermal stability variation of regenerated cellulose. Hydrogen bond acidity and basicity of anti-solvent definitely drove the property variation of regenerated cellulose nanoparticles to opposite directions. Furtherly, we proposed two competitive cellulose regeneration routes, providing a reasonable explanation to the crystallinity, enthalpy in cellulose degradation and thermal stability variation of regenerated cellulose nanoparticles. Our work successfully demonstrate that H-bond acidity/basicity of anti-solvent could tune the property of regenerated cellulose nanoparticles, unveiling the competitive routes of cellulose regeneration.
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