期刊
CATALYSIS TODAY
卷 332, 期 -, 页码 69-75出版社
ELSEVIER
DOI: 10.1016/j.cattod.2018.06.022
关键词
Nitrogen oxides; H-2-SCR; Pd-Au/TiO2; In-situ DRIFTS
资金
- National Natural Science Foundation of China [21377010, 21611130170]
- Beijing Municipal Natural Science Foundation [8162030]
- Royal Society International Exchange Grant [IE150856]
Au promoted Pd/TiO2 catalysts with different Pd loading were investigated for the selective catalytic reduction of NOx by hydrogen (H-2-SCR). The results showed that 1% Pd-0.5% Au/TiO2 catalyst exhibited the highest NOx conversion and N-2 selectivity, as well as a wide activity temperature window. Moreover, the 1% Pd-0.5% Au/TiO2 catalyst offered remarkable resistance to high gas hourly space velocity (GHSV). XRD, XPS and TEM results illustrated that the excellent H-2-SCR performance of 1% Pd-0.5% Au/TiO2 catalyst was closely related to the formed PdAu alloy and the higher dispersion of active sites compared with 1% Pd/TiO2. In-situ DRIFTS results revealed that more and new adsorbed nitrogen oxides species, as well as more adsorbed NH3 and NH4+ active species generated over 1% Pd-0.5% Au/TiO2 catalyst, thus accelerating the ability to active H-2 atom and the subsequent reaction with adsorbed nitrogen oxides species.
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