期刊
CATALYSIS TODAY
卷 306, 期 -, 页码 121-127出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2017.03.040
关键词
ZSM-5/SBA-15 composite; Pt(0.5 wt.%)/Al-SBA-15 and Pt(0.5 wt.%)/ZSM-5/SBA-15 catalysts; Hydrocracking and hydroisomerization of n-decane
资金
- Vietnam National Foundation for Science and Technology Development (NAFOSTED) [104.05-2014.21]
- Spanish Government-MINECO through Severo Ochoa [SEV 2012-0267, CTQ2015-70126-R]
Al-SBA-15 and ZSM-5/SBA-15 (ZSC) composite were synthesized following hydrothermal procedures in the presence of triblock copolymer Poly(ethylene glycol)- poly(propylene glycol)-poly(ethylene glycol) (Pluronic P123) and a mixture of tetrapropylammonium bromide (TPABr)/Pluronic P123 templates, respectively. Pt (0.5 wt.%)/Al-SBA-15 and ZSC bifunctional catalysts were then prepared by a wet impregnation methodology and investigated in the hydrocracking/hydroisomerization of n-decane. Pt/ZSC, containing a trimodal porous texture and high Bronsted acidity, exhibited hydrocracking activity while Pt/Al-SBA-15, showing merely Lewis acidity, was active for hydroisomerization. At 300 degrees C the conversion of n-decane on Pt/ZSC reached 98% and cracking selectivity was about 99%. Both catalysts were exhaustively characterized.
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