期刊
CATALYSIS LETTERS
卷 148, 期 7, 页码 1848-1855出版社
SPRINGER
DOI: 10.1007/s10562-018-2396-2
关键词
5-Hydroxymethylfurfural; Phosphoric carbon; Heterogeneous catalysis
资金
- National Natural Science Foundation of China [21406020]
- Natural Science Foundation of Jiangsu Province [BK20140257]
It is very important to prepare bio-based chemicals from biomass in an eco-friendly and economical process. Herein, a simple and efficient route was proposed to synthesize the phosphoric carbons via one-pot hydrothermal method using glucose as carbon precursor in an aqueous H3PO4 solution. The experimental results presented that the acid density and surface area of the phosphoric carbons were adjustable and showed excellent catalytic activity for biochemical 5-hydroxymethylfurfural (HMF) production from fructose dehydration. 93.7 and 80.9% HMF yield was obtained over the carbon material in DMSO (solvent) and 2-butanol-H2O biphasic system under the investigated reaction conditions, respectively. The cost-efficient solid acids phosphoric carbon with adjustable acidity density have been synthesized, and the catalysts show good performances on 5-hydromethylfurfural (HMF) production from fructose. 93% of HMF yield was obtained catalyzed by phosphoric carbon in DMSO system. [GRAPHICS] .
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据