期刊
CATALYSIS COMMUNICATIONS
卷 112, 期 -, 页码 26-30出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2018.04.014
关键词
Lanthanide aryloxide; Hydroboration; Carbonyl compound; Chemoselectivity; DFT calculation
资金
- National Natural Science Foundation of China [21372171, 21642004, 21674070]
- PAPD
The lanthanide aryloxides Ln(OAr) 3 (THF) 2 (Ar = Ar-1 = 2,6-Bu-t(2)-4-MeC6H2, Ln = Yb (1), Y (2); Ar = Ar-2 = 2,6(t)Pr(2)C(6)H(3), Ln = Y (3); Ar = Ar-3 = 2,6-Me2C6H3, Ln = Y (4); Ar = Ar-1, Ln = Sm (5), Nd (6)) could be served as highly efficient catalysts for the hydroboration of aldehydes and ketones with good functional group tolerance and excellent chemoselectivity. Computational studies were carried out to probe a feasible mechanism of the Ln-aryloxides catalyzed hydroboration of aldehydes/ketones.
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