期刊
CATALYSIS COMMUNICATIONS
卷 114, 期 -, 页码 46-50出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2018.06.002
关键词
Catalytic hydrogenation; Carbon nanoglobules; Palladium catalysts; Ethyl 4-nitrobenzoate; Benzocaine
资金
- Russian Foundation for Basic Research [16-29-10742]
The palladium catalysts prepared using carbon nanoglobules (CNGs) as the support and containing no more than 2 wt% Pd were shown to be highly effective for the liquid-phase hydrogenation of ethyl 4-nitrobenzoate under mild conditions. Regardless of the kind of CNGs and the catalyst preparation method, the most of the Pd/CNGs catalysts allow achieving a complete conversion of substrate giving benzocaine in a 100% yield. The Pd/CNGs catalyst is easily recycled many times without loss of its catalytic performance. The results obtained may be useful for the development of effective Pd/C catalysts for chemoselective hydrogenation of various nitroarenes.
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