期刊
CATALYSIS COMMUNICATIONS
卷 112, 期 -, 页码 1-4出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2018.04.010
关键词
NH3 oxidation; NH imido intermediate; Ammonia dehydrogenation mechanism
资金
- National Natural Science Foundation [U1609212, 51621005]
- Special Funding of Jiangsu Province for Scientific and Technological Achievements Transformation [BA2014127]
NH3 oxidation over V-0.5Ce(SO4)(2)/Ti catalyst used for NH3-SCR was investigated and compared to that occurred over a commercial V-W/Ti catalyst. It was found that much more significant NH3 oxidation into N-2 and N2O occurs over V-0.5Ce(SO4)(2)/Ti than commercial V-W/T-i catalyst at high temperatures (> 300 degrees C). According to the kinetics and characterization results obtained, stronger surface redox properties and a relatively higher concentration of polymerized vanadates present on V-0.5Ce(SO4)(2)/Ti should contribute to its higher NH3 conversion values. In-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) studies suggested the formation of -NH imido species, based on which a successive NH3 dehydrogenation-like mechanism is proposed, which consistently explains well the experimental observations.
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