期刊
CARBOHYDRATE POLYMERS
卷 194, 期 -, 页码 208-216出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2018.04.046
关键词
Halloysite nanotubes; Chitosan; Laccase; Laccase-loaded nanotubular reactors; Nanobiocatalysis; Sustainable environmental cleanup
资金
- Dongguk University, Seoul, South Korea
- Ministry of Education and National Research Foundation of Korea [NRF-2016R1A2B4010431, NRF-2015M2A7A1000194]
- Ministry of Environment [2017001970003]
Halloysite nanotubes (HNTs) were modified with supermagnetic Fe3O4 (M-HNTs) and functionalized with chitosan (CTA) (termed as M-HNTs-CTA). Furthermore, M-HNTs-CTA were cross-linked using glutaraldehyde and applied for covalent laccase immobilization (M-HNTs-CTA-Lac). Facile-synthesized modified HNTs were structurally characterized by scanning electron microscopy, high resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analyses. M-HNTs-CTA-Lac exhibited 92.74 mg/g of laccase immobilization capacity and 92% of activity recovery. Biochemical properties of M-HNTs-CTA-Lac exhibited higher pH and temperature stabilities, with exceptional reusability capabilities until the 11th cycle. Moreover, M-HNTs-CTA-Lac exhibited 87% of 2,2'-azinobis (3-ethylbenzthiazoline-6-sulphonic acid) (ABTS)mediated Direct Red 80 (DR80) decolorization. By the 11th cycle, M-HNTs-CTA-Lac exhibited 33% DR80 decolorization. Therefore, M-HNTs-CTA can function as CTA-modified supermagnetic nonreactors for immobilization of biomacromolecules. The investigated M-HNTs-CTA-Lac are thus biocompatible and environment-friendly biocatalysts for degradation of textile waste, such as DR80, and can be rapidly retrieved from aqueous solution by a magnet after decontamination of environmental pollutants.
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