期刊
BIORESOURCE TECHNOLOGY
卷 263, 期 -, 页码 49-57出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2018.04.101
关键词
Adsorption; Bioremediation; Heavy metals; Microalgae; Toxic elements
资金
- Junta de Castilla y Leon - JCyL, Spain [UIC 071]
- Ministerio de Economia y Competitividad - MINECO - FEDER program [CTQ2017-84006-C3-1-R]
- Junta de Castilla y Leon - JCyL [VA094U14]
- National Commission of Science & Technology (CONICYT) of Chile [21140576]
This work represents a comparative uptake study of the toxic elements arsenic, boron, copper, manganese and zinc in monometallic and multimetallic solutions by four green microalgae species (Chlamydomonas reinhardtii, Chlorella vulgaris, Scenedesmus almeriensis and an indigenous Chlorophyceae spp.), evaluating the effect of pH and contact time. Maximum removal efficiencies for each toxic element were 99.4% for Mn (C. vulgaris, pH 7.0, 3 h), 91.9% for Zn (Chlorophyceae spp., pH 5.5, 3 h), 88% for Cu (Chlorophyceae spp., pH 7.0, 10 min), 40.7% for As (S. almeriensis, pH 9.5, 3 h) and 38.6% for B (S. almeriensis, pH 5.5, 10 min). B removal efficiencies decreased remarkably in multimetallic solutions (down to 0.2% in C. reinhardtii), except for Chlorophyceae spp., the only species isolated from a polluted environment. FTIR spectra shown the highest interactions for As (1150-1300 cm(-1)) and Cu (3300, 1741, 1535, 1350-1400 cm(-1)). Results confirm microalgae biomass as a potential biosorbent for toxic elements.
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