期刊
BIORESOURCE TECHNOLOGY
卷 249, 期 -, 页码 16-23出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2017.09.210
关键词
Co-pyrolysis; Thermogravimetric analysis; Kinetic; Tar
资金
- National Natural Science Foundation of China [51621005]
- Environment Protection Special Funds for Public Welfare [201509013]
In this work, typical organic food waste (soybean protein (SP)) and typical chlorine enriched plastic waste (polyvinyl chloride (PVC)) were chosen as principal MSW components and their interaction during co-pyrolysis was investigated. Results indicate that the interaction accelerated the reaction during co-pyrolysis. The activation energies needed were 2-13% lower for the decomposition of mixture compared with linear calculation while the maximum reaction rates were 12-16% higher than calculation. In the fixed-bed experiments, interaction was observed to reduce the yield of tar by 2-69% and promote the yield of char by 13-39% compared with linear calculation. In addition, 2-6 times more heavy components and 61-93% less nitrogen-containing components were formed for tar derived from mixtures.
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