期刊
BIOPROCESS AND BIOSYSTEMS ENGINEERING
卷 41, 期 4, 页码 573-583出版社
SPRINGER
DOI: 10.1007/s00449-018-1892-5
关键词
Lipases; Solid-state fermentation; Rhizopus microsporus; Esterification; Biodiesel
资金
- CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico, Brasil)
- CAPES (Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior, Brasil)
A fermented solid containing lipases was produced by solid-state fermentation of Rhizopus microsporus on sugarcane bagasse enriched with urea, soybean oil, and a mineral solution. The dry fermented solid produced using R. microsporus (RMFS) was used to catalyze the synthesis of alkyl-esters by esterification in a solvent-free system containing ethanol and oleic acid (as a model system) or a mixture of fatty acids obtained from the physical hydrolysis of soybean soapstock acid oil (FA-SSAO) in subcritical water. The conversions were 93.5 and 84.1%, for oleic acid and FA-SSAO, respectively, at 48 h and 40 A degrees C, at a molar ratio (MR) of ethanol to fatty acid of 5:1. A further increase in the MR to 10:1 improved the production of ethylic-esters, giving conversions at 48 h of 98 and 86% for oleic acid and FA-SSAO, respectively. The results obtained in this work foster further studies on scaling-up of an environmentally friendly process to produce biofuels.
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