期刊
PHYSICAL REVIEW A
卷 93, 期 2, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.93.022509
关键词
-
资金
- University of Sussex
A method is presented for determining inner- and outer-electron radial density functions for two-electron systems by partitioning the fully correlated, two-electron, radial density function. This is applied to the helium isoelectronic series (Z = 1 to 10 and 100) and the critical nuclear charge system, which has the minimum charge for which the atomic system has at least one bound state, to separate out the motions of the two electrons in both weakly and strongly bound systems. It is found that the inner electron experiences a negative screening effect due to the perturbation by the other electron. This is quantified and shown to increase with increasing Z. For the weakly bound systems the inner radial density distribution closely resembles that of a hydrogenic atom with the outer radial density distribution becoming very diffuse.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据