期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 14, 期 -, 页码 1813-1825出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.14.154
关键词
asymmetric catalysis; functionalization of alkenes; hypervalent iodine(III)
资金
- National Nature Science Foundation of China [21532009, 21672236, 21790330, 21761142010]
- National Basic Research Program of China [973-2015CB856600]
- Shanghai Rising-Star Program [17QA1405200]
- Strategic Priority Research Program [XDB20000000]
- Key Research Program of Frontier Science of the Chinese Academy of Sciences [QYZDJSSW-SLH055]
Hypervalent iodine(III) reagents have been well-developed and widely utilized in functionalization of alkenes, however, generally either stoichiometric amounts of iodine(III) reagents are required or stoichiometric oxidants such as mCPBA are employed to in situ generate iodine(III) species. In this review, recent developments of hypervalent iodine(III)-catalyzed functionalization of alkenes and asymmetric reactions using a chiral iodoarene are summarized.
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