期刊
CHEMCATCHEM
卷 8, 期 7, 页码 1269-1273出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201501379
关键词
alcohols; deposition; nanotubes; oxidation; palladium
资金
- Deutsche Forschungsgemeinschaft (DFG) [EXC1069]
- International Max Planck Research School for Surface and Interface Engineering in Advanced Materials (IMPRS-SurMat)
Pd nanoparticles supported on carbon nanotubes were applied in the selective oxidation of ethanol in the liquid phase. The characterization of the surface and bulk properties combined with the catalytic tests indicated the dissolution and redeposition of Pd under the reaction conditions. A dynamic interplay within the Pd life cycle was identified to be responsible for the overall reactivity. Nitrogen-doped carbon nanotubes were found to act as an excellent support for the Pd catalyst system by efficiently stabilizing and recapturing the Pd species, which resulted in high activity and selectivity to acetic acid.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据