Co-catalyst free Titanate Nanorods for improved Hydrogen production under solar light irradiation

Harnessing solar energy for water splitting into hydrogen (H-2) and oxygen (O-2) gases in the presence of semiconductor catalyst is one of the most promising and cleaner methods of chemical fuel (H-2) production. Herein, we report a simplified method for the preparation of photo-active titanate nanorods catalyst and explore the key role of calcination temperature and time period in improving catalytic properties. Both as-synthesized and calcined material showed rod-like shape and trititanate structure as evidenced from crystal structure and morphology analysis. Notably, calcination process affected both length and diameter of the nanorods into shorter and smaller size respectively. In turn, they significantly influenced the band gap reduction, resulting in visible light absorption at optimized calcination conditions. The calcined nanorods showed shift in optical absorption band edge towards longer wave length than pristine nanorods. The rate of hydrogen generation using different photocatalysts was measured by suspending trititanate nanorods (in the absence of co-catalyst) in glycerol-water mixture under solar light irradiation. Among the catalysts, nanorods calcined at 250(a similar to)C for 2 hours recorded high rate of H-2 production and stability confirmed for five cycles. Photocatalytic properties and plausible pathway responsible for improved H-2 production are discussed in detail.