期刊
APPLIED SURFACE SCIENCE
卷 433, 期 -, 页码 610-616出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2017.10.081
关键词
Bi2O2CO3; ZnFe2O4; Magnetic photocatalyst; Z-scheme system
类别
资金
- Key Scientific and Technological Project of Henan Province [172102210347]
- Key Scientific Research Project of Higher Education of Henan Province [18A150035]
Chiral cage compounds are mainly constructed from chiral precursors or based on the symmetry breaking during coordination-driven self-assembly. Herein, we present a strategy to construct chiral organic cages by restricting the P or M rotational configuration of tetraphenylethylene (TPE) faces through dynamic covalent chemistry. The combination of graph theory, experimental characterizations and theoretical calculations suggests emergent chirality of cages is originated from complex arrangements of TPE faces with different orientational and rotational configurations. Accompanied by the generation of chirality, strong fluorescence also emerged during cage formation, even in dilute solutions with various solvents. In addition, the circularly polarized luminescence of the cages is realized as a synergy of their dual chiral and fluorescence properties. Chirality and fluorescence of cages are remarkably stable, because intramolecular flipping of phenyl rings in TPE faces is restricted, as indicated by calculations. This study provides insight into construct chiral cages by the rational design through graph theory, and might facilitate further design of cages and other supramolecular assemblies from aggregation-induced emission active building blocks.
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