期刊
APPLIED SURFACE SCIENCE
卷 436, 期 -, 页码 111-116出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2017.11.288
关键词
Cotton fabric; Flexible SERS substrate; Large-scale production; Sensitivity; Swabbing
类别
资金
- National Natural Science Foundation of China [51203018, 21671037, 51503033]
- Fundamental Research Funds for the Central Universities [2232015D3-14]
The large-scale surface enhanced Raman scattering (SERS) cotton fabrics were fabricated based on traditional woven ones using a dyeing-like method of vat dyes, where silver nanoparticles (Ag NPs) were in-situ synthesized by 'dipping-reducing-drying' process. By controlling the concentration of AgNO3 solution, the optimal SERS cotton fabric was obtained, which had a homogeneous close packing of Ag NPs. The SERS cotton fabric was employed to detect p-Aminothiophenol (PATP). It was found that the new fabric possessed excellent reproducibility (about 20%), long-term stability (about 57 days) and high SERS sensitivity with a detected concentration as low as 10(-12) M. Furthermore, owing to the excellent mechanical flexibility and good absorption ability, the SERS cotton fabric was employed to detect carbaryl on the surface of an apple by simply swabbing, which showed great potential in fast trace analysis. More importantly, this study may realize large-scale production with low cost by a traditional cotton fabric. (C) 2017 Elsevier B.V. All rights reserved.
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