3D structured Mo-doped Ni3S2 nanosheets as efficient dual-electrocatalyst for overall water splitting

Searching for a cost-effective, high efficient and stable bifunctional electrocatalyst for overall water splitting is critical to renewable energy systems. In this study, three-dimensional (3D) curved nanosheets of Mo-doped Ni3S2 grown on nickel foam were successfully synthesized via a one-step hydrothermal process. The hydrogen-evolution reaction (HER) and the oxygen-evolution reaction (OER) in alkaline environment of this 3D catalyst are investigated in detail. The results show that it possesses lower overpotential, high current densities and small Tafel slopes both in OER and HER. For HER, the catalysts show excellent electrochemical performance, demonstrating a low over-potential of 212 mV at 10 mA cm(-2) with a large decrease of 127 mV compared to the undoped Ni3S2. And it also shows a lower over potential of 260 mV at 10 mA cm(-2) which decreases 30 mV for OER. In addition, it is only need 1.67 V for the overall water splitting at 10 mA cm(-2) which is 70 mV. It found that the Mo element would change the morphology of Ni3S2 and induce much more active sites for HER and OER. The as-prepared Mo-doped Ni3S2 bi-functional electrocatalyst could act as the promising electrode materials for water splitting. (C) 2018 Elsevier B.V. All rights reserved.