期刊
APPLIED SURFACE SCIENCE
卷 439, 期 -, 页码 11-17出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2018.01.067
关键词
HKUST-1; CuO/Cu2O; Core-shell; Glucose sensor
类别
资金
- National Natural Science Foundation of China [51402081, 51502071, 51772072, 51272063]
- Fundamental Research Funds for the Central Universities [JZ2016HGTB0719, JZ2017HGTB0203]
Self-supported CuO/Cu2O@CuO/Cu2O core-shell nanowire arrays (NWAs) are successfully fabricated by a simple and efficient method in this paper. Anodized Cu(OH)(2) NWAs could in-situ convert to HKUST-1 at room temperature easily. Cu(OH)(2) NWAs cores and HKUST-1 shells transform into CuO/Cu2O simultaneously after calcinations and form CuO/Cu2O@CuO/Cu2O core-shell NWAs. This smart configuration of the core-shell structure not only avoids the agglomeration of the traditional MOF-derived materials in particle-shape, but also facilitates the ion diffusion and increases the active sites. This novel structure is employed as substrate to construct nonenzymatic glucose sensors. The results indicate that glucose sensor based on CuO/Cu2O@CuO/Cu2O core-shell NWAs presents ultrahigh sensitivity (10,090 lA mM(-1) cm(-2)), low detection limit (0.48 lM) and wide linear range (0.99-1,330 lM). In addition, it also shows excellent anti-interference ability toward uric acid, ascorbic acid and L-Cysteine co-existing with glucose, good reproducibility and superior ability of real sample analysis. (C) 2018 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据