期刊
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
卷 124, 期 5, 页码 -出版社
SPRINGER
DOI: 10.1007/s00339-018-1814-z
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资金
- Madhya Pradesh Council of Science and Technology, Madhya Pradesh, India [Bhopal] [3683/CST/R&D/PhyEngg.Sc/2012]
Different concentrations of potassium iodide (KI) as redox additive had been added to 1 M sulfuric acid (H2SO4) electrolyte with an aim of enhancing the capacitance and energy density of ultracapacitors via redox reactions at the interfaces of electrode-electrolyte. Ultracapacitors were fabricated using chemically treated activated carbon as electrode with H2SO4 and H2SO4-KI as an electrolyte. The electrochemical performances of fabricated supercapacitors were investigated by impedance spectroscopy, cyclic voltammetry and charge-discharge techniques. The maximum capacitance 'C' was observed with redox additives-based electrolyte system comprising 1 M H2SO4-0.3 M KI (1072 F g(-1)), which is very much higher than conventional 1 M H2SO4 (61.3 F g(-1)) aqueous electrolyte-based ultracapacitors. It corresponds to an energy density of 20.49 Wh kg(-1) at 2.1 A g(-1) for redox additive-based electrolyte, which is six times higher as compared to that of pristine electrolyte (1 M H2SO4) having energy density of only 3.36 Wh kg(-1). The temperature dependence behavior of fabricated cell was also analyzed, which shows increasing pattern in its capacitance values in a temperature range of 5-70 degrees C. Under cyclic stability test, redox electrolyte-based system shows almost 100% capacitance retention up to 5000 cycles and even more. For comparison, ultracapacitors based on polymer gel electrolyte polyvinyl alcohol (PVA) (10 wt%)-{H2SO4 (1 M)-KI (0.3 M)} (90 wt%) have been fabricated and characterized with the same electrode materials.
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