期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 32, 期 5, 页码 -出版社
WILEY
DOI: 10.1002/aoc.4307
关键词
ethylene diamine; metal-organic framework; multi-component; solid base catalyst; UiO-66
资金
- Center for International Scientific Studies & Collaboration (CISSC)
This study demonstrates ED-UiO-66 as a novel and effective solid nanoporous basic catalyst prepared through the amine grafting onto the pores of UiO-66. The manufactured nanoparticles were identified by FT-IR, XRD, TGA, FESEM, TEM, CHN and BET and the characterization results certified formation of a single phase nanoporous substance with the medium grain size less than 90 nm. The synthesized material was employed as an efficient catalyst for the preparation of 2-aminotiophenes through the Gewald method. This thermochemically stable nanocatalyst was environmentally safe, reusable and economic. Therefore, this methodology can be simply extended for industrial goals.
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