期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 222, 期 -, 页码 115-123出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2017.10.014
关键词
Carbon quantum dots; Bi2WO6; OD/2D heterojunction; Full spectrum light; Interface engineering; Density functional theory
资金
- National Natural Science Foundation of China [51579096, 51521006, 51222805, 51679084, 51508175, 51409024]
- National Program for Support of Top-Notch Young Professionals of China
- Program for New Century Excellent Talents in University from the Ministry of Education of China [NCET-11-0129]
A novel full spectrum light driven carbon quantum dots (CQDs)/Bi2WO6 (CBW) hybrid materials were synthesized via a facile hydrothermal method. Multiple techniques including XRD, TEM, XPS, BET, UV-vis, XPS, PL and TRPL, were employed to investigate the structures, morphology, optical and electronic properties and photocatalytic performance of as-prepared samples. The results indicated that CBW heterojunctions were assembly of CQDs on m-BWO and presented high separation efficiency of photo-generated carriers and full light spectrum absorption. The photocatalytic mechanism of CBW hybrid materials was revealed, suggesting that the excellent photocatalytic activity towards organic pollutants was ascribed to the up converted photoluminescence (PL) and electron reservoir properties of CQDs. Density functional theory calculations indicated that complementary conduction and valence band-edge hybridization between CQDs and m-BWO could apparently increase separation efficiency of electron-hole pairs of CBW hybrid materials. According to ESR measurement and quenching experiments, the O-2 center dot(-), center dot OH and h(+) were the main active species during the photocatalytic process. This study could shed light on OD/2D interface engineering of carbon quantum dots based heterojunctions with enhanced photoactivity for full spectrum light utilization in pollutant degradation and energy conversion.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据