期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 224, 期 -, 页码 295-304出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2017.10.064
关键词
Deactivation; Phosphorus; Phosphine; Hydrogenation; Nickel
资金
- National Research Foundation of South Africa
- Electron Microscopy Unit at the University of KwaZulu-Natal
The effectiveness of different experiments for the regeneration of a phosphorus poisoned 15 wt.% Ni/Al2O3 catalyst was investigated during the time on stream hydrogenation of octanal to octanol. The catalyst was deactivated after being exposed to feed contaminated with 500 ppm of triphenylphosphine. Regeneration of the catalyst was attempted by either treating the poisoned catalyst with hydrogen, washing the catalyst with octanol or conducting a combined octanol wash-hydrogen treatment experiment, all at elevated temperatures and at atmospheric pressure. The combined regeneration experiment was the most effective, since the conversion and octanol selectivity were recovered to a significant extent. Characterisation of the regenerated catalysts by ICP-OES, XRD, magnetic measurements and TEM showed that sintering also contributed to the deactivation of the catalysts, and that regeneration did not remove phosphorus from the catalyst, due to phosphorus having reacted with nickel. It was also established that some phosphorus was incorporated into the alumina support to generate strongly acidic sites.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据