期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 227, 期 -, 页码 190-197出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcatb.2018.01.007
关键词
Metal-organic framework; NH2-MIL-125; Amorphous TiO2; CdS quantum dots; Visible photocatalyst
资金
- National Natural Science Foundation of China [NSFC-51578488]
- Special Program for Social Development of Key Science and Technology Project of Zhejiang Province [2014C03025]
- Zhejiang Provincial 151 Talents Program
- Program for Zhejiang Leading Team of ST Innovation [2013TD07]
- Changjiang Scholar Incentive Program (Ministry of Education, China)
Metal-organic frameworks (MOFs) are of significant interest for photocatalysis using visible light. Here we discuss HOMO/LUMO gap modification of amine-functionalized MOFs through a mild one-step method. DFT calculation reveals the formation of covalent bond between TiO2 and the amine from NH2-MIL-125, narrowing the HOMO/LUMO gap of NH2-MIL-125 by raising its HOMO level. After CdS quantum dots (QDs) deposited on this MOF@TiO2 core-shell structure, this composite catalyst can act as an efficient visible-light-driven catalyst for NO removal. The integral coating of amorphous TiO2 onto MOF octahedrons constructs a mesoporous protection shell upon MOF frameworks, providing a superior accommodation for embedding CdS QDs. Integrating MOF with TiO2 also reduces undesirable electron-hole recombination by facilitating charge transfer to amorphous TiO2. Possible mechanism of photocatalytic oxidation of NO over CdS/NH2-MIL-125@TiO2 catalysts is proposed. This work illustrates the possibility of tuning the optical response of NH2-MOFs under very mild condition, and demonstrates the potential usage of MOF-based heterostructured photocatalysts.
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