期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 6, 页码 1712-1716出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712019
关键词
C-H activation; cycloisomerization; cyclopropene; furans; rhodium(III) catalysis
资金
- Alexander von Humboldt Foundation
A novel and efficient strategy for the synthesis of arylated furans was successfully developed by a Rh-III-catalyzed coupling of N-phenoxyacetamides and cyclopropenyl esters. Mechanistic investigation reveals that the arylated furans are formed via arylation of the cyclopropenyl esters followed by cycloisomerization.
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