期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 30, 页码 9456-9460出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201802782
关键词
amination; amines; boronic acids; hydroxylamines; trichloroacetonitrile
资金
- National Natural Science Foundation [21602145, 21772125]
- 1000 Talent plan program
- Sichuan University
We have found that readily available N-alkyl hydroxylamines are effective reagents for the amination of organoboronic acids in the presence of trichloroacetonitrile. This amination reaction proceeds rapidly at room temperature and in the absence of added metal or base, it tolerates a remarkable range of functional groups, and it can be used in the late-stage assembly of two complex units.
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