期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 6, 页码 1543-1546出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201710707
关键词
amination; carbometalation; cyclopropanols; cyclopropylamines; oxidation
资金
- European Research Council under the Seventh Framework Program of the European Community (ERC Grant) [338912]
The catalytic asymmetric carbometalation of cyclopropenes followed by either an electrophilic oxidation or amination reaction provides a unique approach to the formation of diastereomerically pure and enantiomerically enriched cyclopropanol and cyclopropylamine derivatives, respectively.
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