期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 36, 页码 11776-11780出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805936
关键词
anions; cyclic alkyl(amino) carbenes; germanylidene; phosphinidene; silanylidene
资金
- DNRF [DNRF93]
- DFG [RO 224/68-1]
- CSIR, India
- bilateral DST-DFG Scheme [INT/FRG/DFG/P-05/2017]
- SERB India
The reduction of TipMCl(3) (Tip=2,4,6-triisopropylphenyl) (M=Si, Ge) with KC8 in the presence of cyclic alkyl(amino) carbene (cAAC) afforded the acyclic silanylidene and germanylidene anions in the form of potassium salt [K(cAAC)MTip](2) (M=Si (1); Ge (2)). The silanylidene and germanylidene anions are valence-isoelectronic to the well-studied phosphinidene and are a new class of acyclic anions of Group 14. Compounds 1 and 2 were isolated and well characterized by NMR and single-crystal X-ray structure analysis. Furthermore, the structure and bonding of compounds 1 and 2 was investigated by computational methods.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据