期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 15, 页码 3862-3873出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201709684
关键词
asymmetric synthesis; carbenes; cycloaddition; organocatalysis; reaction mechanisms
资金
- China Scholarship Council
N-heterocyclic carbene (NHC) catalysis has emerged as a powerful strategy in organic synthesis. In recent years a number of reviews have been published on NHC-catalyzed transformations involving Breslow intermediates, acyl azoliums, alpha,beta-unsaturated acyl azoliums, homoenolate equivalents, and azolium enolates. However, the azolium dienolate intermediates generated by NHCs have been employed in asymmetric synthesis only very recently, especially in cycloadditions dealing with remote functionalization. This Minireview highlights all the developments and the new advances in NHC-catalyzed asymmetric cycloaddition reactions involving azolium dienolate intermediates.
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