期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 14, 页码 3682-3686出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201713324
关键词
asymmetric catalysis; boronic acids; carbometalation; cyclopropanes; rhodium
资金
- European Research Council [338912]
- European Research Council (ERC) [338912] Funding Source: European Research Council (ERC)
A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.
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