期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 7, 页码 1933-1938出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712139
关键词
ab initio calculations; dysprosium; luminescence; magnetic properties; structure determination
资金
- European Union's Horizon research and innovation program (Marie Sklodowska Curie grant) [800719]
- U.S. National Science Foundation [CHE-1464841]
- NSF
- Office of Science, Office of Basic Energy Sciences, of the U.S. DOE [DE-AC02-05CH11231]
- NIH Shared Instrumentation Grant [S10-RR027172]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464841] Funding Source: National Science Foundation
The first dysprosium complexes with a terminal fluoride ligand are obtained as air-stable compounds. The strong, highly electrostatic dysprosium-fluoride bond generates a large axial crystal-field splitting of the J = 15/2 ground state, as evidenced by high-resolution luminescence spectroscopy and correlated with the single-molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.
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