期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 7, 页码 1869-1873出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201711040
关键词
dynamic covalent chemistry; interfaces; olefin metathesis; surface chemistry; scanning tunneling microscopy
资金
- National Science Foundation of China [21572157, 51633006]
- Ministry of Science and Technology of China [2016YFB0401100]
- University of Colorado Boulder
- K. C. Wong Education Foundation
Understanding how the constitutional dynamics of a dynamic combinatorial library (DCL) adapts to surfaces (compared to bulk solution) is of fundamental importance to the design of adaptive materials. Submolecular resolved scanning tunneling microscopy (STM) can provide detailed insights into olefin metathesis at the interface. Analysis of the distribution of products has revealed the important role of environmental pressure, reaction temperature, and substituent effects in surface-confined olefin metathesis. We also report an unprecedented preferred deposition and assembly of linear polymers, and some specific oligomers, on the surface that are hard to obtain otherwise.
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