期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 9, 页码 2450-2454出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712718
关键词
anode; arene coupling; electrochemistry; molybdenum; oxidative coupling
资金
- DFG [Wa1276/151]
- Center for INnovative and Emerging MAterials (CINEMA)
- Verband der Chemischen Industrie (VCI)
- Deutscher Akademischer Austauschdienst (DAAD/RISE)
A new and powerful active anode system that can be operated in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher-valent molybdenum species. This system can replace powerful but stoichiometrically required Mo-V reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据