期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 32, 页码 10132-10136出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201804401
关键词
block copolymers; head-tail asymmetry; inverse phases; self-assembly; solvent effects
资金
- National Natural Science Foundation of China [51725301]
The self-assembly of a rod-coil amphiphilic block copolymer (ABCP) led to Im3m and Pn3m polymer cubosomes and p6mm polymer hexasomes. This is the first time that these structures are observed in a rod-coil system. By varying the hydrophobic chain length, the initial concentration of the polymer solution, or the solubility parameter of the mixed solvent, head-tail asymmetry is adjusted to control the formation of polymer cubosomes or hexasomes. The formation mechanism of the polymer cubosomes was also studied. This research opens up a new way for further study of the bicontinuous and inverse phases in different ABCP systems.
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