期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 29, 页码 8968-8972出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201803721
关键词
beryllium; borates; deep ultraviolet light; nonlinear optics; second harmonic generation
资金
- National Natural Science Foundation of China [51425205, U1605245, 51602309]
- National Key Research and Development Plan of Ministry of Science and Technology [2016YFB0402104]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
KBe2BO3F2 (KBBF) is still the only practically usable crystal that can generate deep-ultraviolet (DUV) coherent light by direct second harmonic generation (SHG). However, applications are hindered by layering, leading to difficulty in the growth of thick crystals and compromised mechanical integrity. Despite efforts, it is still a great challenge to discover new nonlinear optical (NLO) materials that overcome the layering while keeping the DUV SHG available. Now, two new DUV NLO beryllium borates have been successfully designed and synthesized, NH4Be2BO3F2 (ABBF) and -Be2BO3F (-BBF), which not only overcome the layering but also can be used as next-generation DUV NLO materials with the shortest typeI phase-matching second-harmonic wavelength down to 173.9nm and 146nm, respectively. Significantly, -BBF is superior to KBBF in all metrics and would be the most outstanding DUV NLO crystal.
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