期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 11, 页码 2938-2942出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712811
关键词
aldehydes; ketones; carbenes; palladium; synthetic methods
资金
- JSPS KAKENHI Grant [JP15H03803, JP17H06449]
- Grants-in-Aid for Scientific Research [17K15422] Funding Source: KAKEN
Benzylation and allylation of aldehyde acyl anions were enabled by the merger of a thiazolium N-heterocyclic carbene (NHC) catalyst and a palladium/bisphosphine catalyst in a synergistic manner. Owing to the mildness of the reaction conditions, various functional groups were tolerated in the substrates.
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