期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 20, 页码 5695-5698出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201801106
关键词
alkenes; aziridines; electrochemistry; radicals; synthetic methods
资金
- State Key Laboratory Cultivation Base for TCM Quality and Efficacy, Nanjing University of Chinese Medicine [TCMQ E 201702]
- National Science Foundation of China [21572099, 21332005]
- Natural Science Foundation of Jiangsu Province [BK20151379]
The first direct aziridination of triaryl-substituted alkenes was achieved by means of an electrochemical process that could extend to multisubstituted styrenes. Specifically, hexafluoroisopropanol sulfamate was used as a nucleophilic nitrogen source. Mechanistic experiments suggest that this electrochemical process proceeds by stepwise formation of two C-N bonds through reactions between cationic carbon species and the sulfamate.
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