期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 10, 页码 2712-2715出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712775
关键词
cyclizations; hydrogen-atom transfer; palladium; photochemistry; radicals
资金
- National Institutes of Health [GM120281]
- National Science Foundation [CHE-1663779]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM120281] Funding Source: NIH RePORTER
A novel mild, visible-light-induced palladium-catalyzed hydrogen atom translocation/atom-transfer radical cyclization (HAT/ATRC) cascade has been developed. This protocol involves a 1,5-HAT process of previously unknown hybrid vinyl palladium radical intermediates, thus leading to iodomethyl carbo- and heterocyclic structures.
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