期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 20, 页码 5684-5689出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201800820
关键词
flexible microporous materials; ligand contortion; methane storage; stepped adsorption isotherm
资金
- Science Foundation Ireland (SFI) [13/RP/B2549]
- National Research Foundation of South Africa
- Claude Leon Foundation
- National Science Foundation [CHE-1152362]
- Major Research Instrumentation Program [CHE-1531590]
- XSEDE Grant [TG-DMR090028]
- Japan Society of the Promotion of Science (JSPS) [25000007]
- ACCEL program of Japan Science and Technology Agency (JST)
- Division Of Chemistry [1531590] Funding Source: National Science Foundation
Herein, we report that a new flexible coordination network, NiL2 (L=4-(4-pyridyl)-biphenyl-4-carboxylic acid), with diamondoid topology switches between non-porous (closed) and several porous (open) phases at specific CO2 and CH4 pressures. These phases are manifested by multi-step low-pressure isotherms for CO2 or a single-step high-pressure isotherm for CH4. The potential methane working capacity of NiL2 approaches that of compressed natural gas but at much lower pressures. The guest-induced phase transitions of NiL2 were studied by single-crystal XRD, insitu variable pressure powder XRD, synchrotron powder XRD, pressure-gradient differential scanning calorimetry (P-DSC), and molecular modeling. The detailed structural information provides insight into the extreme flexibility of NiL2. Specifically, the extended linker ligand, L, undergoes ligand contortion and interactions between interpenetrated networks or sorbate-sorbent interactions enable the observed switching.
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