期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 20, 页码 5917-5920出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201712944
关键词
bond analysis; kinetic stabilization; lead; reductive elimination; transmetallation
资金
- Deutsche Forschungsgemeinschaft (DFG)
Transmetallation of Pb(OAc)(4) with R2Hg (1), followed by treatment with HCl in Et2O, provided RPbCl3 (2), the first kinetically stabilized monoorganolead trihalide that resists reductive elimination under ambient conditions. The kinetic stabilisation relies on an intramolecularly coordinating O-donor substituent (R = 6-Ph2P(O)-Ace-5-). The gram-scale preparation of 2 was key for the synthesis of unsymmetrically substituted diaryllead dichlorides RR'PbCl2 (3 a, R' = Ph; 3 b, R' = 4-MeOC6H4; 3 c, R' = 4-Me2NC6H4).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据